Trichloromethanesulfenyl chloride → Methyl[(trichloromethyl)sulfanyl]carbamyl fluoride

Reaction equation

[CH3:1][NH:2][C:3]([F:5])=[O:4].[Cl:6][C:7]([Cl:11])([Cl:10])[S:8]Cl.CCOP(OC1C=CC2C(C)=CC(OC=2C=1)=O)(OCC)=S>>[CH3:1][N:2]([S:8][C:7]([Cl:11])([Cl:10])[Cl:6])[C:3]([F:5])=[O:4]

Participants

Reactant 3

HCID 11666Trichloromethanesulfenyl chloride

HCID 10496498O,O-Diethyl O-(4-methyl-2-oxo-2H-1-benzopyran-7-yl) phosphorothioate

HCID 12545956Methylcarbamyl fluoride

Product 1

HCID 12836648Methyl[(trichloromethyl)sulfanyl]carbamyl fluoride

Procedure

N-Methyl-N-trichloromethanesulfenylcarbamoyl fluoride was prepared from methylcarbamoyl fluoride and trichloromethanesulfenyl chloride according to the method reported in West Germany Pat. No. 1.297,095 (Farbenfabriken Bayer, A. G), June 12, 1969.

Sources & evidence

ORD record: ord-0388dd647e5a431fb1044755311288ea
Source dataset: uspto-grants-1976_05
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US03956500

Reaction notes

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