Acetylene → HCID 11830456, compound
Reaction equation
[CH3:1][Si:2]([CH3:11])([CH3:10])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][OH:9].[OH-].[K+].[CH:14]#[CH:15]>CS(C)=O>[CH:14]([O:9][CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][CH2:3][Si:2]([CH3:1])([CH3:10])[CH3:11])=[CH2:15]Participants
5
Reactant 3
Product 1
Reagents, catalysts & solvents 1
Procedure
In a similar manner to Example 1, 75 g (0.43 mol) of 6-(trimethylsilyl)hexanol, 7.5 g of KOH and 75 g of DMSO were reacted at 80° C. with acetylene. 6-(Trimethylsilyl)hexyl vinyl ether was obtained in 99% yield.
Sources & evidence
- ORD record
- ord-72b075e6647b44a6bf2ed5412c09cce7
- Source dataset
- uspto-grants-1996_12
- Patent number
- US05587503
Reaction notes
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