Toluene → HCID 23693107, compound

HRID 1089641

Reaction equation

HRID 1089641 reaction equation
C(OC)(=O)C1C=CC(C([O-])=O)=CC=1.[K+:14].[C:15]([O:28]CC)(=[O:27])[C:16]1[CH:26]=[CH:25][C:19]([C:20]([O:22][CH2:23][CH3:24])=[O:21])=[CH:18][CH:17]=1.[OH-].[K+].C1(C)C=CC=CC=1>C(O)C>[C:20]([O:22][CH2:23][CH3:24])(=[O:21])[C:19]1[CH:25]=[CH:26][C:16]([C:15]([O-:28])=[O:27])=[CH:17][CH:18]=1.[K+:14]

Participants

6

Reactant 4

HCID 1140TolueneHCID 12483Diethyl terephthalateHCID 14797Potassium HydroxideHCID 236837531,4-Benzenedicarboxylic acid, 1-methyl ester, potassium salt (1:1)

Product 1

HCID 23693107HCID 23693107, compound

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

This compound was prepared by the procedure described for potassium monomethyl terephthalate. Typical reagent levels were as follows: 77.0 gm (0.346 mole) of diethyl terephthalate, 19.4 gm of potassium hydroxide, 150 ml of toluene and 100 ml of ethanol.

Workup

  1. customThis compound was prepared by the procedure

Sources & evidence

ORD record
ord-6fc1ab55849247b0a645d3cb5ff02d94
Source dataset
uspto-grants-1992_01
Patent number
US05078907

Linked notes

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