Butyl(dimethyl)silane → 11-(Butyldimethylsilyl)undecyl glycidyl ether

HRID 1100

Reaction equation

HRID 1100 reaction equation
[CH2:1]([O:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH:15]=[CH2:16])[CH:2]1[O:4][CH2:3]1.[CH2:17]([SiH:21]([CH3:23])[CH3:22])[CH2:18][CH2:19][CH3:20]>>[CH2:1]([O:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][Si:21]([CH2:17][CH2:18][CH2:19][CH3:20])([CH3:23])[CH3:22])[CH:2]1[O:4][CH2:3]1

Participants

3

Reactant 2

HCID 2757279Butyl(dimethyl)silaneHCID 10353667Oxirane, [(10-undecenyloxy)methyl]-

Product 1

HCID 1969462511-(Butyldimethylsilyl)undecyl glycidyl etherYield 82.6%

Conditions

Temperature
60 °C

Procedure

A 100-ml flask equipped with a stirrer was charged with 13.6 g (60 mmol) of 10-undecenyl glycidyl ether, 5.8 g (50 mmol) of butyldimethylsilane and 4 mg (0.01 mmol) of H2PtCl6. The contents were stirred at 60° C. for 24 hours. The resultant reaction mixture was distilled under reduced pressure (145°-154° C./6×10-3 Torr), thereby obtaining 14.15 g (yield: 82.6%) of 11-(butyldimethylsilyl)undecyl glycidyl ether.

Workup

  1. customA 100-ml flask equipped with a stirrer
  2. customThe resultant reaction mixture
  3. distillationwas distilled under reduced pressure (145°-154° C./6×10-3 Torr)

Sources & evidence

ORD record
ord-3d817c6e53494262853c2c135e11aa2f
Source dataset
uspto-grants-1998_03
Patent number
US05723497

Linked notes

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