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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1138Generated: October 23, 2026

Methyl 4-Iodo-3-methylbenzoate → Methyl 3-methyl-4-(5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-anthryl)benzoate

https://huagongshe.com/en/reaction/1138

Reaction equation

Participants

RoleNameHCIDCharge
ReactantMethyl 4-Iodo-3-methylbenzoateHCID 231757—
Reactant5,6,7,8-Tetrahydro-5,5,8,8-tetramethyl-2-anthrylboronic acidHCID 19694676—
ProductMethyl 3-methyl-4-(5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-anthryl)benzoateHCID 1969468753%

Reaction Steps

Following the basic procedure of Example 7(f), by reacting 2.8 g (10 mmol) of 5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-anthrylboronic acid with 1.84 g (6.7 mmol) of methyl 3-methyl-4-iodobenzoate, 1.37 g (53%) of methyl 3-methyl-4-(5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-anthryl)benzoate was obtained in the form of a yellow oil.

Provenance & Evidence

DOI10.6084/m9.figshare.5104873.v1
Patent numberUS05723499
Source datasetuspto-grants-1998_03
ORD IDord-7949d567ab7542a8990b7bcf17a467de
Source noteuspto-grants-1998_03