Cerium(III) chloride → HCID 20436360, compound

Reaction equation

C[O:2][C:3]1[CH:12]=[CH:11][C:10]([O:13]C)=[C:9]2[C:4]=1[N:5]=[CH:6][CH:7]=[N:8]2.[Cl-:15].[Ce+3].[Cl-].[Cl-]>>[Cl:15][C:12]1[CH:3]=[C:4]([CH:9]=[CH:10][CH:11]=1)[NH:5][C:12]1[C:3](=[O:2])[C:4]2[N:5]=[CH:6][CH:7]=[N:8][C:9]=2[C:10](=[O:13])[CH:11]=1

Participants

Reactant 2

HCID 24636Cerium(III) chloride

HCID 600389HCID 600389, compound

Product 1

HCID 20436360HCID 20436360, compound

Procedure

Following the procedure of Example 5,3-chloroaniline was reacted with the aqueous solution of 5,8-dimethoxyquinoxaline in the presence of cerium chloride to give the title compound. Mass spectrum gave M+ of 285 and 287.

Sources & evidence

ORD record: ord-1260faadac054d7c907b514b076851a3
Source dataset: uspto-grants-1984_12
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04486432

Reaction notes

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