Zirconium(IV) propoxide → Zirconium 3-cyanopropylphosphonate

HRID 1155179Notes

Reaction equation

HRID 1155179 reaction equation
C[Si]([O:5][P:6]([CH2:13][CH2:14][CH2:15][C:16]#[N:17])(=[O:12])[O:7][Si](C)(C)C)(C)C.[O-]CCC.[O-]CCC.[O-]CCC.[O-]CCC.[Zr+4:34]>C(Cl)(Cl)(Cl)Cl>[Zr:34].[C:16]([CH2:15][CH2:14][CH2:13][P:6](=[O:5])([O-:12])[O-:7])#[N:17]

Participants

4

Reactant 2

HCID 90139Zirconium(IV) propoxideHCID 20562954Bistrimethylsilyl-3-cyanopropylphosphonate

Product 1

HCID 86738104Zirconium 3-cyanopropylphosphonate

Reagents, catalysts & solvents 1

HCID 5943Carbon TetrachlorideSolvent

Conditions

Temperature
60 °C

Procedure

A 2.5 ml portion of the above prepared bistrimethylsilyl-3-cyanopropylphosphonate solution in CCl4 was added dropwise 0.049 g of zirconium tetra propoxide. The reaction mixture was heated to 60° C. and filtered. The filtrate was saved. About 0.058 g of zirconium-3-cyanopropylphosphonate was formed.

Workup

  1. filtrationfiltered

Sources & evidence

ORD record
ord-d08d503e35b748858bde3cec2426b89d
Source dataset
uspto-grants-1981_11
Patent number
US04299943

Reaction notes

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