Ethyl bromoacetate → Ethyl (6,7-dibromo-1-oxo-2-phenyl-5-indanyloxy)acetate

Reaction equation

[Br:1][C:2]1[C:10]([Br:11])=[C:9]2[C:5]([CH2:6][CH:7]([C:13]3[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=3)[C:8]2=[O:12])=[CH:4][C:3]=1[OH:19].Br[CH2:21][C:22]([O:24][CH2:25][CH3:26])=[O:23]>>[Br:1][C:2]1[C:10]([Br:11])=[C:9]2[C:5]([CH2:6][CH:7]([C:13]3[CH:14]=[CH:15][CH:16]=[CH:17][CH:18]=3)[C:8]2=[O:12])=[CH:4][C:3]=1[O:19][CH2:21][C:22]([O:24][CH2:25][CH3:26])=[O:23]

Participants

Reactant 2

HCID 7748Ethyl bromoacetate

HCID 205371386,7-Dibromo-5-hydroxy-2-phenyl-1-indanone

Product 1

HCID 54007940Ethyl (6,7-dibromo-1-oxo-2-phenyl-5-indanyloxy)acetate

Procedure

Reaction of 6,7-dibromo-5-hydroxy-2-phenyl-1-indanone with ethyl bromoacetate according to the procedure of Example 1, STEP (a), affords the title compound.

Sources & evidence

ORD record: ord-1f5b633224d248d1a2c76028b2d6b66a
Source dataset: uspto-grants-1982_06
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04334088

Reaction notes

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