Allyl bromide → 4-Allyloxy-3-nitrobenzaldehyde

HRID 1176216

Reaction equation

[OH:1][C:2]1[CH:9]=[CH:8][C:5]([CH:6]=[O:7])=[CH:4][C:3]=1[N+:10]([O-:12])=[O:11].[CH2:13](Br)[CH:14]=[CH2:15]>>[CH2:15]([O:1][C:2]1[CH:9]=[CH:8][C:5]([CH:6]=[O:7])=[CH:4][C:3]=1[N+:10]([O-:12])=[O:11])[CH:14]=[CH2:13]

Participants

Reactant 2

HCID 7841Allyl bromide

HCID 181694-Hydroxy-3-nitrobenzaldehyde

Product 1

HCID 224011524-Allyloxy-3-nitrobenzaldehyde

Procedure

Analogously to Method F, 25 g of 4-hydroxy-3-nitrobenzaldehyde and 25.1 ml of allyl bromide are reacted. The title compound is obtained as a slightly yellowish solid. Rf=0.30 (1:2 EtOAc-heptane). Rt=4.00.

Sources & evidence

ORD record: ord-ee9a3375b8094033afe57a6e5cbb414d
Source dataset: uspto-grants-2010_11
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US07842688B2

Linked notes

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