Acetic Acid → 2,6-Diacetoxynaphthalene

HRID 1194599

Reaction equation

HRID 1194599 reaction equation
[OH:1][C:2]1[CH:11]=[CH:10][C:9]2[C:4](=[CH:5][CH:6]=[C:7]([OH:12])[CH:8]=2)[CH:3]=1.[C:13](OC(=O)C)(=[O:15])[CH3:14].[C:20](O)(=[O:22])[CH3:21]>>[C:13]([O:1][C:2]1[CH:11]=[CH:10][C:9]2[C:4](=[CH:5][CH:6]=[C:7]([O:12][C:20](=[O:22])[CH3:21])[CH:8]=2)[CH:3]=1)(=[O:15])[CH3:14]

Participants

4

Reactant 3

HCID 176Acetic AcidHCID 7918Acetic AnhydrideHCID 935522,6-Dihydroxynaphthalene

Product 1

HCID 5949302,6-Diacetoxynaphthalene

Procedure

In the same manner as in Example 7, 0.6 g of the thus obtained 2,6-dihydroxynaphthalene were acetylated with 0.27 g of acetic acid and 0.79 g of acetic anhydride to obtain 0.83 g of 2,6-diacetoxynaphthalene of the purity of 99.80% (by DSC).

Sources & evidence

ORD record
ord-8db01b79955b4d48a11c83707883462a
Source dataset
uspto-grants-1989_03
Patent number
US04814521

Linked notes

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