Cyclohexane → Ethyl 2-chloro-2-fluorocyclopropanecarboxylate

HRID 120369

Reaction equation

HRID 120369 reaction equation
[CH2:1]([C:2]1=[N:10][CH:5]([C:6]([CH3:7])([CH3:8])[CH3:9])[CH2:4][O:3]1)[C:11]1=[N:19][CH:14]([C:15]([CH3:16])([CH3:17])[CH3:18])[CH2:13][O:12]1.[CH2:32]1[CH2:33][CH2:34][CH2:35][CH2:36][CH2:37]1.[Cl:20][C:21](=[CH2:22])[F:23].[Cu+2:46].[F:38][C:39]([F:40])([F:41])[S:42]([O-:43])(=[O:44])=[O:45].[F:47][C:48]([F:49])([F:50])[S:51]([O-:52])(=[O:53])=[O:54].[N+:24](=[N-:25])=[CH:26][C:27](=[O:28])[O:29][CH2:30][CH3:31]>>[Cl:20][C:21]1([F:23])[CH2:22][CH:26]1[C:27](=[O:28])[O:29][CH2:30][CH3:31]

Participants

7

Reactant 6

HCID 8078CyclohexaneHCID 12192Ethyl diazoacetateHCID 27099Cupric cationHCID 753441-Chloro-1-fluoroetheneHCID 2758875Trifluoromethanesulfonate2×HCID 34799334-Tert-butyl-2-[(4-tert-butyl-4,5-dihydro-1,3-oxazol-2-yl)methyl]-4,5-dihydro-1,3-oxazole

Product 1

HCID 9793930Ethyl 2-chloro-2-fluorocyclopropanecarboxylate

Sources & evidence

ORD record
ord-4f5f4450110349d99bc0feb6c5b8cf5f
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (2/10)

Linked notes

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