Ethyl 2-oxocyclohexanecarboxylate → Ethyl 3-bromo-2-oxocyclohexanecarboxylate

HRID 12041

Reaction equation

HRID 12041 reaction equation
[CH2:1]([O:3][C:4]([CH:6]1[CH2:11][CH2:10][CH2:9][CH2:8][C:7]1=[O:12])=[O:5])[CH3:2].[Br:13]C1CC(C(C)C)CCC1=O>>[CH2:1]([O:3][C:4]([CH:6]1[CH2:11][CH2:10][CH2:9][CH:8]([Br:13])[C:7]1=[O:12])=[O:5])[CH3:2]

Participants

3

Reactant 2

HCID 95543Ethyl 2-oxocyclohexanecarboxylateHCID 627080672-Bromo-4-isopropyl-cyclohexanone

Product 1

HCID 121765Ethyl 3-bromo-2-oxocyclohexanecarboxylate

Procedure

The bromination of 2-oxo-cyclohexane carboxylic acid ethyl ester takes place in a manner similar to that described above for the preparation of 2-bromo-4-isopropyl-cyclohexanone. The title compound is reacted as a crude product without further characterization.

Sources & evidence

ORD record
ord-37fb364ca93b408f8103ecfca7b9d4ae
Source dataset
uspto-grants-2010_06
Patent number
US07727979B2

Linked notes

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