Acetate → 4-{4-[5-(benzyloxy)pyridin-3-yl]-9H-carbazol-9-yl}-2-fluorobenzonitrile

HRID 1214733

Reaction equation

HRID 1214733 reaction equation
[Br:1][c:2]1[cH:3][c:4]([F:10])[c:5]([C:6]#[N:7])[cH:8][cH:9]1.[C:11](=[O:12])([O-:13])[O-:14].[C:50]([O-:51])(=[O:52])[CH3:53].[C:55]([O-:56])(=[O:57])[CH3:58].[CH2:17]([c:18]1[cH:19][cH:20][cH:21][cH:22][cH:23]1)[O:24][c:25]1[cH:26][c:27](-[c:31]2[cH:32][cH:33][cH:34][c:35]3[nH:36][c:37]4[cH:38][cH:39][cH:40][cH:41][c:42]4[c:43]23)[cH:28][n:29][cH:30]1.[Cs+:15].[Cs+:16].[O:44]1[CH2:45][CH2:46][O:47][CH2:48][CH2:49]1.[Pd+2:54]>>[c:2]1(-[n:36]2[c:35]3[cH:34][cH:33][cH:32][c:31](-[c:27]4[cH:26][c:25]([O:24][CH2:17][c:18]5[cH:19][cH:20][cH:21][cH:22][cH:23]5)[cH:30][n:29][cH:28]4)[c:43]3[c:42]3[c:37]2[cH:38][cH:39][cH:40][cH:41]3)[cH:3][c:4]([F:10])[c:5]([C:6]#[N:7])[cH:8][cH:9]1

Participants

8

Reactant 7

HCID 175Acetate2×HCID 19660Carbonate IonHCID 312751,4-DioxaneHCID 104967Cesium cation2×HCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)HCID 7360294-Bromo-2-fluorobenzonitrileHCID 673086444-[5-(benzyloxy)pyridin-3-yl]-9H-carbazole

Product 1

HCID 673091964-{4-[5-(benzyloxy)pyridin-3-yl]-9H-carbazol-9-yl}-2-fluorobenzonitrile

Sources & evidence

ORD record
ord-616061ed265e4a24acd5746d8b264f45
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (5/10)

Linked notes

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