2-Hexyloctyl amine → HCID 178443157, compound

HRID 1261706Notes

Reaction equation

HRID 1261706 reaction equation
[CH2:1]([CH:11]([CH2:63][CH2:64][CH2:65][CH2:66][CH2:67][CH2:68]CCCCCC)[CH2:12][N:13]=[C:14]([C:16]1[C:25]2[C:24]([C:26]([OH:28])=[O:27])=[C:23]([Br:29])[C:22]([Br:30])=[C:21]([C:31]([OH:33])=[O:32])[C:20]=2[C:19]([C:34](=[N:36][CH2:37][CH:38]([CH2:51][CH2:52][CH2:53][CH2:54][CH2:55][CH2:56]CCCC)[CH2:39][CH2:40][CH2:41][CH2:42][CH2:43][CH2:44]CCCCCC)[OH:35])=[C:18]([Br:61])[C:17]=1[Br:62])[OH:15])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6]CCCC.C(C(CCCCCC)CN)CCCCC>>[CH2:51]([CH:38]([CH2:39][CH2:40][CH2:41][CH2:42][CH2:43][CH3:44])[CH2:37][N:36]=[C:34]([C:19]1[C:20]2[C:21]([C:31]([OH:33])=[O:32])=[C:22]([Br:30])[C:23]([Br:29])=[C:24]([C:26]([OH:28])=[O:27])[C:25]=2[C:16]([C:14](=[N:13][CH2:12][CH:11]([CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH3:6])[CH2:63][CH2:64][CH2:65][CH2:66][CH2:67][CH3:68])[OH:15])=[C:17]([Br:62])[C:18]=1[Br:61])[OH:35])[CH2:52][CH2:53][CH2:54][CH2:55][CH3:56]

Participants

3

Reactant 2

HCID 226771852-Hexyloctyl amineHCID 178442862HCID 178442862, compound

Product 1

HCID 178443157HCID 178443157, compoundYield 22%

Procedure

The same synthetic method for compound 22 was used except using 2-hexyloctyl amine instead of 2-decyltetradecyl amine, and the yield was 22% (calculated based on TBNDA as a starting material).

Sources & evidence

ORD record
ord-38709881cfc249cbaeb03b5526ab4ff5
Source dataset
uspto-grants-2013_06
Patent number
US08471021B2

Reaction notes

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