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Cyclododecanone, 2-ethenyl- → HCID 5375859, compound

HRID 1266682
Notes
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Reaction equation

HRID 1266682 reaction equation
[CH:1]([CH:3]1[CH2:14][CH2:13][CH2:12][CH2:11][CH2:10][CH2:9][CH2:8][CH2:7][CH2:6][CH2:5][C:4]1=[O:15])=[CH2:2].C(=C1/C(=O)CCCCCCCCCC/1)/C>>[CH:1](=[C:3]1/[C:4](=[O:15])[CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14]/1)\[CH3:2]
ParticipantsProcedureSources & evidenceReaction notes

Participants

3

Reactant 2

HCID 11820381Cyclododecanone, 2-ethenyl-2×HCID 12068246HCID 12068246, compound

Product 1

HCID 5375859HCID 5375859, compound

Procedure

On the other hand, 2-vinylcyclododecanone (2) which is the object product is one having the lowest boiling point among the components of the equilibrated mixture. Specifically, the average relative volatility of each of these components is as follows though it varies depending on temperature: when the boiling point is 110° C., the average relative volatility of each of 2-(Z)-ethylidenecyclododecanone (1-b) and 2-vinylcyclododecanone (2) is 1.15 and 1.44, respectively provided that the average relative volatility of 2-(E)-ethylidenecyclododecanone (1-a) is defined as 1.00.

Sources & evidence

ORD record
ord-73d7dd31fa55438e9f081b1f9aafcbe3
Source dataset
uspto-grants-2003_04
DOI
10.6084/m9.figshare.5104873.v1
Patent number
US06548711B2

Reaction notes

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On this pageParticipantsProcedureSources & evidenceReaction notes