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Dichloromethane → N-(4-methoxybenzyl)-4,5-difluoro-2-hydroxybenzamide

HRID 1271045
Notes
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Reaction equation

HRID 1271045 reaction equation
[F:1][C:2]1[C:10]([F:11])=[CH:9][C:5]([C:6]([OH:8])=O)=[C:4]([OH:12])[CH:3]=1.[C:13]([O:16][C:17](=O)[CH3:18])(=O)C.Cl[CH2:21]Cl.[N+]([C:26]1[CH:32]=[CH:31][C:29]([NH2:30])=CC=1)([O-])=O>N1C=CC=CC=1>[CH3:13][O:16][C:17]1[CH:18]=[CH:21][C:31]([CH2:29][NH:30][C:6](=[O:8])[C:5]2[CH:9]=[C:10]([F:11])[C:2]([F:1])=[CH:3][C:4]=2[OH:12])=[CH:32][CH:26]=1
ParticipantsProcedureWorkupSources & evidenceReaction notes

Participants

6

Reactant 4

HCID 6344DichloromethaneHCID 74754-NitroanilineHCID 7918Acetic AnhydrideHCID 120408324,5-Difluoro-2-hydroxybenzoic acid

Product 1

HCID 18452522N-(4-methoxybenzyl)-4,5-difluoro-2-hydroxybenzamideYield 85%

Reagents, catalysts & solvents 1

HCID 1049
Pyridine
Solvent

Procedure

To a solution 4,5-difluoro-2-hydroxybenzoic acid (1 g, 6 mmol, prepared by the method of Kazuto Umezv, U.S. Pat. No. 6,166,246) in pyridine (2 mL) was added acetic anhydride (0.8 mL, 7 mol) and the mixture was stirred at room temperature for 2 hr. To this added 10% HCl (10 mL) and extracted with ethyl acetate. The ethyl acetate was evaporated and the residue taken up in dichloromethane (10 mL). To this solution was added oxalyl chloride (1 mL) and few drops of dimethylformamide and stirred for 1 hr at room temperature. The solvent was removed and the acid chloride was re-dissolved in dichloromethane (10 mL) followed by the slow addition to a dichloromethane solution (10 mL) of p-nitroaniline (0.880 mL, 6.5 mmol). The reaction mixture after 2 hr showed new peak by HPLC and complete disappearance of the starting material. The dichloromethane was removed and the residue dissolved in methanol and to it added 10% aqueous NaOH solution (3 mL) and mixture stirred for 1 hr. The methanol was removed and the residue acidified and extracted with ethyl acetate. The ethyl acetate layer was dried, filtered and evaporated to yield 1.5 g (85%) of N-(4-methoxybenzyl)-4,5-difluoro-2-hydroxybenzamide as a white solid. RP-HPLC: 2.67 min; ES-MS (M+H)+=295.0; 1H-NMR (DMSO-d6) δ (ppm): 6.8 (dd, 1 H), 7.9 (dd, 1 H), 7.94 (d, 2 H), 8.24 (d, 2 H).

Workup

  1. extractionTo this added 10% HCl (10 mL) and extracted with ethyl acetate
  2. customThe ethyl acetate was evaporated
  3. additionTo this solution was added oxalyl chloride (1 mL) and few drops of dimethylformamide
  4. stirringstirred for 1 hr at room temperature
  5. customThe solvent was removed
  6. dissolutionthe acid chloride was re-dissolved in dichloromethane (10 mL)
  7. waitThe reaction mixture after 2 hr showed new
  8. customThe dichloromethane was removed
  9. dissolutionthe residue dissolved in methanol and to it
  10. additionadded 10% aqueous NaOH solution (3 mL) and mixture
  11. stirringstirred for 1 hr
  12. customThe methanol was removed
  13. extractionextracted with ethyl acetate
  14. dry with materialThe ethyl acetate layer was dried
  15. filtrationfiltered
  16. customevaporated

Sources & evidence

ORD record
ord-4a3b69ab12ff43829c79799a396c270c
Source dataset
uspto-grants-2007_04
DOI
10.6084/m9.figshare.5104873.v1
Patent number
US07205296B2

Reaction notes

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