Methanethiol → HCID 21519568, compound

Reaction equation

[CH:1]12[C:7]([CH3:9])([CH3:8])[CH:6]1[C:5](=[O:10])[CH:4]=[C:3]([CH3:11])[CH2:2]2.[CH3:12][SH:13]>>[CH3:12][S:13][C:3]1([CH3:11])[CH2:4][C:5](=[O:10])[CH:6]2[C:7]([CH3:8])([CH3:9])[CH:1]2[CH2:2]1

Participants

Reactant 2

HCID 878Methanethiol

HCID 135028754,7,7-Trimethylbicyclo[4.1.0]hept-3-en-2-one

Product 1

HCID 21519568HCID 21519568, compound

Procedure

In accordance with the procedure of Example 8 car-3-en-5-one is reacted with methylmercaptan by heating the reaction mixture in a suitable pressure-vessel for 3 hours to yield 3-methylthio-caran-5-on, boiling point ca 70° at 0.5 mm Hg, nD20 = 1.5224.

Workup

temperatureby heating the reaction mixture in a suitable pressure-vessel for 3 hours

Sources & evidence

ORD record: ord-6055fa014a22492197fa6955f172a207
Source dataset: uspto-grants-1976_08
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US03974222

Reaction notes

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