Iodine → titanium(III) trichloride

HRID 128341

Reaction equation

HRID 128341 reaction equation
[Cl-:1].[Cl-].[Cl-].[Ti+3:4].[I:5][I:6].[CH2:7]([O:12][CH2:13][CH2:14][CH:15]([CH3:17])[CH3:16])[CH2:8][CH:9]([CH3:11])[CH3:10]>C1(C)C=CC=CC=1>[Cl-:1].[Cl-:1].[Cl-:1].[Ti+3:4].[I:5][I:6].[CH2:13]([O:12][CH2:7][CH2:8][CH:9]([CH3:11])[CH3:10])[CH2:14][CH:15]([CH3:16])[CH3:17]

Participants

6

Reactant 3

HCID 807IodineHCID 10989Diisopentyl etherHCID 10313229titanium(III) trichloride

Product 2

HCID 10313229titanium(III) trichlorideHCID 131712143I2 di-isoamyl ether

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Procedure

Titanium trichloride composition (A) of 11.0 g was suspended in 55 ml of toluene and iodine and di-isoamyl ether were added in amounts to give a molar ratio of titanium trichloride composition (A)/I2 /di-isoamyl ether of 1.0/0.1/1.0 and then reacted at 80° C. for one hour to obtain titanium trichloride solid catalyst. This catalyst is referred to as titanium trichloride solid catalyst (II).

Sources & evidence

ORD record
ord-54247050930040fab4b17de526a68ef3
Source dataset
uspto-grants-1981_03
Patent number
US04259461

Linked notes

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