Sulfuryl chloride → 3-(Chloromethoxy)-1,1,1,2,2-pentafluoropropane
Reaction equation
[F:1][C:2]([F:10])([C:6]([F:9])([F:8])[F:7])[CH2:3][O:4][CH3:5].S(Cl)([Cl:14])(=O)=O>CCOCC>[F:1][C:2]([F:10])([C:6]([F:9])([F:8])[F:7])[CH2:3][O:4][CH2:5][Cl:14]Participants
4
Reactant 2
Product 1
Reagents, catalysts & solvents 1
Procedure
The ether V can be prepared by a method analogous to that described by Weinmayr1, or from methyl 2,2,3,3,3-pentafluoropropyl ether and one molar equivalent of sulfuryl chloride at 0°-35° C with ultraviolet irradiation to give the chloromethyl 2,2,3,3,3-pentafluoropropyl ether XXVII,
Sources & evidence
- ORD record
- ord-48566f25405548028f6d758a4e99dce0
- Source dataset
- uspto-grants-1976_08
- Patent number
- US03976788
Reaction notes
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