8-Hydroxyquinoline → Aluminium tri(quinolin-8-olate)

HRID 1370984Notes

Reaction equation

HRID 1370984 reaction equation
O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.S([O-])([O-])(=O)=O.[Al+3:22].S([O-])([O-])(=O)=O.S([O-])([O-])(=O)=O.[Al+3].[OH:34][C:35]1[CH:36]=[CH:37][CH:38]=[C:39]2[C:44]=1[N:43]=[CH:42][CH:41]=[CH:40]2.[OH-].[Na+]>O>[CH:37]1[CH:36]=[C:35]([O-:34])[C:44]2[N:43]=[CH:42][CH:41]=[CH:40][C:39]=2[CH:38]=1.[CH:37]1[CH:36]=[C:35]([O-:34])[C:44]2[N:43]=[CH:42][CH:41]=[CH:40][C:39]=2[CH:38]=1.[CH:37]1[CH:36]=[C:35]([O-:34])[C:44]2[N:43]=[CH:42][CH:41]=[CH:40][C:39]=2[CH:38]=1.[Al+3:22]

Participants

5

Reactant 3

HCID 19238-HydroxyquinolineHCID 14798Sodium HydroxideHCID 23065692Aluminum sulfate hexadecahydrate

Product 1

HCID 90594Aluminium tri(quinolin-8-olate)Yield 197.6%

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

To 93 g of water were added 25 g of aluminum sulfate hexadecahydrate and 35 g of 99% pure 8-hydroxyquinoline and the mixture was neutralized by dropwise addition of 29 g of a 33% solution of sodium hydroxide with stirring and allowed to react. The solid formed was collected by filtration, washed with water and dried to give 36 g of Alq3.

Workup

  1. customto react
  2. customThe solid formed
  3. filtrationwas collected by filtration
  4. washwashed with water
  5. customdried

Sources & evidence

ORD record
ord-b5b62ed6e0904eb8ba229573dda84fc8
Source dataset
uspto-grants-2003_06
Patent number
US06583583B1

Reaction notes

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