3-Methoxy-1-propanol → Perfluoro 3-methoxypropyl vinyl ether

Reaction equation

[CH3:1][O:2][CH2:3][CH2:4][CH2:5]O.C([O:11][C:12]([C:15](C(OC(C(OC)=O)(C(F)(F)F)F)(F)F)(F)F)(F)F)(F)(F)F.C(OC(C(C(OC(=C(F)F)F)(F)F)(F)F)(F)F)(F)(F)[F:33]>>[CH3:1][O:2][CH2:3][CH2:4][CH2:5][CH:15]=[CH:12][O:11][F:33]

Participants

Reactant 3

HCID 741163-Methoxy-1-propanol

HCID 22613616Hexafluoro-1-trifluoromethoxy-3-trifluorovinyloxypropane

HCID 131722758CF3O(CF2)3OCF(CF3)COOMe

Product 1

HCID 131722757Perfluoro 3-methoxypropyl vinyl ether

Procedure

In a procedure similar to Example 1, CH3O(CH2)3OH was converted to CF3O(CF2)3OCF(CF3)COOMe bp 123-126° C. and this to CF3O(CF2)3OCF═CF2 bp 62-64° C.

Sources & evidence

ORD record: ord-ba18dd42e8974862b480d173a0c85acf
Source dataset: uspto-grants-2001_07
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US06255536B1

Reaction notes

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