1-Bromo-2-nitrobenzene → HCID 23087148, compound

HRID 1433864

Reaction equation

HRID 1433864 reaction equation
Br[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][C:3]=1[N+:8]([O-:10])=[O:9].C([Sn](CCCC)(CCCC)C1C=CC=CC=1[N+]([O-])=O)CCC.FC(F)(F)S(O[C:39]1[CH2:48][CH2:47][C:46]2[C:41](=[CH:42][CH:43]=[C:44]([O:49][CH3:50])[CH:45]=2)[CH:40]=1)(=O)=O>>[CH3:50][O:49][C:44]1[CH:45]=[C:46]2[C:41]([CH:40]=[C:39]([C:2]3[CH:7]=[CH:6][CH:5]=[CH:4][C:3]=3[N+:8]([O-:10])=[O:9])[CH2:48][CH2:47]2)=[CH:42][CH:43]=1

Participants

4

Reactant 3

HCID 113411-Bromo-2-nitrobenzeneHCID 11338886Stannane, tributyl(2-nitrophenyl)-HCID 153302566-Methoxy-3,4-dihydronaphthalen-2-yl trifluoromethanesulfonate

Product 1

HCID 23087148HCID 23087148, compound

Procedure

Synthesized from 1-bromo-2-nitrobenzene according to an analogous synthetic method to Preparation Example 76, tributyl(2-nitrophenyl)tin (7.3 g) and 6-methoxy-3,4-dihydronaphthalen-2-yl trifluoromethanesulfonate (2.2 g) were used according to an analogous synthetic method to Preparation Example 77 to provide the title compound (1.5 g).

Workup

  1. customwere used according to an analogous synthetic method to Preparation Example 77

Sources & evidence

ORD record
ord-b32ce141dc53404ea6e4e18e82ce31b5
Source dataset
uspto-grants-2009_11
Patent number
US07612114B2

Linked notes

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