Thioguaiacol → 2-(Propan-2-yl)benzene-1-sulfonyl chloride

HRID 1440721Notes

Reaction equation

CO[C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][C:4]=1[S:9]([Cl:12])(=[O:11])=[O:10].Cl[C:14]1[CH:15]=CC(OC)=C(S(Cl)(=O)=O)[CH:19]=1.COC1C=CC=CC=1S>>[CH:14]([C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][C:4]=1[S:9]([Cl:12])(=[O:11])=[O:10])([CH3:15])[CH3:19]

Participants

Reactant 3

HCID 23642Thioguaiacol

HCID 27342725-Chloro-2-methoxybenzene-1-sulfonyl chloride

HCID 37458512-Methoxybenzenesulfonyl Chloride

Product 1

HCID 129164822-(Propan-2-yl)benzene-1-sulfonyl chloride

Procedure

A mixture of 2-methoxybenzenesulfonyl chloride and 5-chloro-2-methoxybenzenesulfonyl chloride, which results from ring chlorination, was prepared from 2-methoxythiophenol.

Workup

customresults from ring chlorination

Sources & evidence

ORD record: ord-7971bc8f60b349eb9333678b3a547db5
Source dataset: uspto-grants-1996_03
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05500405

Reaction notes

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