1-Butanaminium, N,N,N-tributyl-, azide → Ethanethioic acid cis-(+/-)-S-[5-(Azidomethyl)tetrahydro-3-furanyl]ester

HRID 1450297Notes

Reaction equation

HRID 1450297 reaction equation
FC(F)(F)S(O[CH2:7][C@H:8]1[O:12][CH2:11][C@@H:10]([S:13][C:14](=[O:16])[CH3:15])[CH2:9]1)(=O)=O.[N-:19]=[N+:20]=[N-:21].C([N+](CCCC)(CCCC)CCCC)CCC>C(Cl)Cl>[N:19]([CH2:7][C@H:8]1[O:12][CH2:11][C@@H:10]([S:13][C:14](=[O:16])[CH3:15])[CH2:9]1)=[N+:20]=[N-:21]

Participants

4

Reactant 2

HCID 57432321-Butanaminium, N,N,N-tributyl-, azideHCID 86750330Ethanethioic acid cis-(+/-)-S-[tetrahydro-5-[[[(trifluoromethyl)-sulfonyl]oxy]methyl]-3-furanyl]ester

Product 1

HCID 86750331Ethanethioic acid cis-(+/-)-S-[5-(Azidomethyl)tetrahydro-3-furanyl]esterYield 87.8%

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent2×

Procedure

The title compound is prepared by the procedure of Example 43 using 0.560 g of product from Example 60 in 2 ml of methylene chloride, 0.569 g of tetrabutylammonium azide in 2 ml of methylene chloride to give 0.321 g of the desired product.

Sources & evidence

ORD record
ord-b5b00e01f41546b0b05bccd21f7a324d
Source dataset
uspto-grants-1997_02
Patent number
US05602118

Reaction notes

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