Methyl Salicylate → HCID 53471241, compound

Reaction equation

[OH:1][C:2]1[CH:11]=[CH:10][CH:9]=[CH:8][C:3]=1[C:4]([O:6]C)=[O:5].[CH2:12](Br)/[CH:13]=[C:14](/[CH2:16][CH2:17][CH:18]=[C:19]([CH3:21])[CH3:20])\[CH3:15]>>[CH2:12]([O:1][C:2]1[CH:11]=[CH:10][CH:9]=[CH:8][C:3]=1[C:4]([OH:6])=[O:5])/[CH:13]=[C:14](/[CH2:16][CH2:17][CH:18]=[C:19]([CH3:21])[CH3:20])\[CH3:15]

Participants

Reactant 2

HCID 4133Methyl Salicylate

HCID 53658672,6-Octadiene, 1-bromo-3,7-dimethyl-, (2E)-

Product 1

HCID 53471241HCID 53471241, compoundYield 75%

Procedure

In a manner similar to Reference Example 1, methyl 2-hydroxybenzoate (7.61 g) was reacted with geranyl bromide (10.9 g) and then hydrolyzed to yield 10.2 g (75%) of 2- geranyloxybenzoic acid.

Sources & evidence

ORD record: ord-87bec9f8c8bf4f89a101215b163e7772
Source dataset: uspto-grants-1998_12
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05849930

Reaction notes

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