Thiophosgene → HCID 19089253, compound
Reaction equation
[NH2:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][C:3]=1[C:8]1[CH:13]=[CH:12][C:11]([O:14][CH3:15])=[CH:10][CH:9]=1.[C:16](Cl)(Cl)=[S:17]>O1CCOCC1.O>[CH3:15][O:14][C:11]1[CH:12]=[CH:13][C:8]([C:3]2[C:2]([N:1]=[C:16]=[S:17])=[CH:7][CH:6]=[CH:5][CH:4]=2)=[CH:9][CH:10]=1Participants
5
Reactant 2
Product 1
Reagents, catalysts & solvents 2
Procedure
Reaction of 2-amino-4'-methoxybiphenyl (10 g) with thiophosgene (8.7 g) in dioxane (25 ml) and water (80 ml) at 0° C. for 3 hours gave 4'-methoxy-2-biphenylylisothiocyanate as a pale yellow oil.
Sources & evidence
- ORD record
- ord-e7127db33d954f6bb9d1a2d3cb176d14
- Source dataset
- uspto-grants-1994_04
- Patent number
- US05302720
Reaction notes
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