2,4-Dimethylbenzenethiol → 1-Bromo-2-(4-methyl-phenylsulfanyl)-5-methyl-benzene

HRID 15197

Reaction equation

HRID 15197 reaction equation
[Br:1][C:2]1[CH:7]=[C:6]([CH3:8])[CH:5]=[CH:4][C:3]=1[S:9][C:10]1[CH:15]=[CH:14][C:13]([CH3:16])=[CH:12][C:11]=1C.CC1C=C(C)C=CC=1S.BrC1C=C(C)C=CC=1I>>[Br:1][C:2]1[CH:7]=[C:6]([CH3:8])[CH:5]=[CH:4][C:3]=1[S:9][C:10]1[CH:11]=[CH:12][C:13]([CH3:16])=[CH:14][CH:15]=1

Participants

4

Reactant 3

HCID 836172,4-DimethylbenzenethiolHCID 6266343-Bromo-4-iodotolueneHCID 686815831-Bromo-2-(2,4-dimethyl-phenylsulfanyl)-5-methyl-benzene

Product 1

HCID 686852301-Bromo-2-(4-methyl-phenylsulfanyl)-5-methyl-benzene

Procedure

1-Bromo-2-(2,4-dimethyl-phenylsulfanyl)-5-methyl-benzene (intermediate for 1 g) Prepared from 2,4-dimethyl-benzenethiol and 2-bromo-1-iodo-4-methyl-benzene.

Sources & evidence

ORD record
ord-dc688289bbe543e09ad2e2f3adb8ee91
Source dataset
uspto-grants-2010_06
Patent number
US07732463B2

Linked notes

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