Formaldehyde → n-Hexylhydroxymethylphosphinic acid, n-butyl ester

HRID 1539

Reaction equation

HRID 1539 reaction equation
[CH2:1]([PH:7](=[O:13])[O:8][CH2:9][CH2:10][CH2:11][CH3:12])[CH2:2][CH2:3][CH2:4][CH2:5][CH3:6].[CH2:14]=[O:15]>>[CH2:1]([P:7]([CH2:14][OH:15])(=[O:13])[O:8][CH2:9][CH2:10][CH2:11][CH3:12])[CH2:2][CH2:3][CH2:4][CH2:5][CH3:6]

Participants

3

Reactant 2

HCID 712FormaldehydeHCID 178418254HCID 178418254, compound

Product 1

HCID 86752200n-Hexylhydroxymethylphosphinic acid, n-butyl ester

Procedure

The title compound was prepared from n-hexylphosphinic acid, n-butyl ester and paraformaldehyde according to the method described in Procedure 31. Purification by chromatography, eluting with dichloromethane containing 5% methanol, gave an oil.

Workup

  1. customPurification by chromatography
  2. washeluting with dichloromethane containing 5% methanol
  3. customgave an oil

Sources & evidence

ORD record
ord-8ac817860d9d44d4acd7988671266af2
Source dataset
uspto-grants-1998_03
Patent number
US05726165

Linked notes

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