Methanol → Sodium ion

HRID 154064

Reaction equation

HRID 154064 reaction equation
[BH4-:69].[CH3:1][O:2][C:3]1=[CH:4][CH:5]=[C:6]2[CH:7]3[CH2:8][c:9]4[cH:10][cH:11][c:12]([O:13][CH3:14])[c:15]5[c:23]4[C:18]2([CH:17]1[O:16]5)[CH2:19][CH2:20][N:21]3[CH3:22].[CH3:45][O:46][C:47]1=[CH:68][C:52]23[C:51](=[CH:50][C:48]1=[O:49])[CH:63]([CH2:62][c:54]1[c:53]2[c:58]([OH:59])[c:57]([O:60][CH3:61])[cH:56][cH:55]1)[N:64]([CH3:65])[CH2:66][CH2:67]3.[CH3:71][OH:72].[CH:24]12[C:25]34[c:26]5[c:27]([cH:35][cH:36][c:37]([OH:38])[c:39]5[O:40][CH:41]3[CH:42]([OH:28])[CH:43]=[CH:44]1)[CH2:29][CH:30]2[N:31]([CH3:34])[CH2:32][CH2:33]4.[Na+:70]>>[CH3:1][O:2][C:3]1=[CH:4][CH:5]=[C:6]2[CH:7]3[CH2:8][c:9]4[cH:10][cH:11][c:12]([O:13][CH3:14])[c:15]5[c:23]4[C:18]2([CH:17]1[O:16]5)[CH2:19][CH2:20][N:21]3[CH3:22].[Na+:70].[OH-:28]

Participants

9

Reactant 6

HCID 887MethanolHCID 923Sodium ionHCID 4253Morphinan-3,6alpha-diol, 7,8-didehydro-4,5alpha-epoxy-17-methyl-HCID 28123BorohydrideHCID 408120Morphinan, 6,7,8,14-tetradehydro-4,5-epoxy-3,6-dimethoxy-17-methyl-, (5alpha)-HCID 6251603-Hydroxy-4,13-dimethoxy-17-methyl-17-azatetracyclo(7.5.3.01,10.02,7)heptadeca-2(7),3,5,10,13-pentaen-12-one

Product 3

HCID 923Sodium ionHCID 961HydroxideHCID 408120Morphinan, 6,7,8,14-tetradehydro-4,5-epoxy-3,6-dimethoxy-17-methyl-, (5alpha)-

Sources & evidence

ORD record
ord-9b656c89f7ef4d6fa75d37cde9611310
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (9/10)

Linked notes

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