Carbonate Ion → Tert-butyl 4-((4-amino-3-nitrophenoxy)methyl)piperidine-1-carboxylate

HRID 155285

Reaction equation

HRID 155285 reaction equation
[C:1](=[O:2])([O-:3])[O-:4].[Cs+:5].[Cs+:6].[NH2:7][c:8]1[c:9]([N+:15](=[O:16])[O-:17])[cH:10][c:11]([OH:14])[cH:12][cH:13]1.[S:18]([O:19][CH2:29][CH:30]1[CH2:31][CH2:32][N:33]([C:36](=[O:37])[O:38][C:39]([CH3:40])([CH3:41])[CH3:42])[CH2:34][CH2:35]1)([c:20]1[cH:21][cH:22][c:23]([CH3:24])[cH:25][cH:26]1)(=[O:27])=[O:28]>>[NH2:7][c:8]1[c:9]([N+:15](=[O:16])[O-:17])[cH:10][c:11]([O:14][CH2:29][CH:30]2[CH2:31][CH2:32][N:33]([C:36](=[O:37])[O:38][C:39]([CH3:40])([CH3:41])[CH3:42])[CH2:34][CH2:35]2)[cH:12][cH:13]1

Participants

5

Reactant 4

HCID 19660Carbonate IonHCID 104967Cesium cation2×HCID 37588824-Amino-3-NitrophenolHCID 106428511-(tert-Butoxycarbonyl)-4-((p-toluenesulfonyloxy)methyl)piperidine

Product 1

HCID 59349493Tert-butyl 4-((4-amino-3-nitrophenoxy)methyl)piperidine-1-carboxylate

Sources & evidence

ORD record
ord-ace35182abf3451691f35b76300e9c82
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (9/10)

Linked notes

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