Methanol → tert-butyl N-hydroxycarbamate

Reaction equation

[C:5]([CH3:6])([CH3:7])([CH3:8])[O:9][C:10](=[O:11])[O:12][C:13]([O-:14])=[O:15].[CH3:16][OH:17].[N:1](=[N+:2]=[N-:3])[OH:4].[OH-:18].[OH-:19].[Pd+2:20]>>[NH:1]([OH:4])[C:10]([O:9][C:5]([CH3:6])([CH3:7])[CH3:8])=[O:11]

Participants

Reactant 5

HCID 887Methanol

HCID 961Hydroxide2×

HCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)

HCID 18670949Hydroxy azide

HCID 22064466Tert-butyldicarbonate

Product 1

HCID 97534tert-butyl N-hydroxycarbamate

Sources & evidence

ORD record: ord-418c479dca31499d85d567781ba7be10
Source dataset: Training data from https://doi.org/10.1039/C8SC04228D (1/10)
DOI: 10.1039/C8SC04228D

Reaction notes

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