1-Chloro-3-(chloromethoxy)benzene → HCID 86733986, compound

Reaction equation

[NH2:1][C:2]1[NH:3][C:4]2[C:10]([CH3:11])=[CH:9][CH:8]=[CH:7][C:5]=2[N:6]=1.[Cl:12][CH2:13][O:14][C:15]1[CH:20]=[CH:19][CH:18]=[C:17]([Cl:21])[CH:16]=1>>[Cl-:12].[NH2:1][C:2]1[N:6]([CH2:13][O:14][C:15]2[CH:20]=[CH:19][CH:18]=[C:17]([Cl:21])[CH:16]=2)[C:5]2[CH:7]=[CH:8][CH:9]=[C:10]([CH3:11])[C:4]=2[N+:3]=1[CH2:13][O:14][C:15]1[CH:20]=[CH:19][CH:18]=[C:17]([Cl:21])[CH:16]=1

Participants

Reactant 2

HCID 215111811-Chloro-3-(chloromethoxy)benzene

HCID 178423998HCID 178423998, compound

Product 1

HCID 86733986HCID 86733986, compound

Procedure

Following the procedure of Example 2 and replacing 2-aminobenzimidazole with 2-amino-4-methylbenzimidazole and replacing 2-bromo-4-chlorophenyl chloromethyl ether with 3-chlorophenyl chloromethyl ether, the title compound is obtained.

Sources & evidence

ORD record: ord-3a86603e447d4624ab7687e6ebd8806d
Source dataset: uspto-grants-1976_09
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US03981886

Reaction notes

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