Hydroxycitronellal → 6,10-Dimethylundeca-3-en-2-on-10-ol
Reaction equation
[CH3:1][CH:2]([CH2:10][CH:11]=O)[CH2:3][CH2:4][CH2:5][C:6]([OH:9])([CH3:8])[CH3:7]>CC(C)=O>[CH3:1][CH:2]([CH2:3][CH2:4][CH2:5][C:6]([CH3:7])([OH:9])[CH3:8])[CH2:10][CH:11]=[CH:5][C:6](=[O:9])[CH3:7]Participants
3
Reactant 1
Product 1
Reagents, catalysts & solvents 1
Procedure
Ethynylation of 212 g of 6,10-dimethylundeca-3-en-2-on-10-ol obtained by aldol condensation of hydroxycitronellal and acetone was carried out in the same manner as in example 20 except that hydroxycitronellal was used in place of pseudoionone and 269 g of a crude product was thus obtained.
Sources & evidence
- ORD record
- ord-9acb2cf4a40948bba0d43a9326517ce1
- Source dataset
- uspto-grants-1976_09
- Patent number
- US03981930
Reaction notes
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