Methanone, (3-hydroxybenzo[b]thien-2-yl)phenyl- → HCID 178449011, compound

Reaction equation

[C:1]([C:9]1[S:13][C:12]2[CH:14]=[CH:15][CH:16]=[CH:17][C:11]=2[C:10]=1[OH:18])(=O)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.C([O-])(=O)C.[CH2:23]([NH3+:27])[CH2:24][CH2:25][CH3:26]>>[CH2:23]([NH:27]/[C:1](/[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1)=[C:9]1\[C:10](=[O:18])[C:11]2[CH:17]=[CH:16][CH:15]=[CH:14][C:12]=2[S:13]\1)[CH2:24][CH2:25][CH3:26]

Participants

Reactant 2

HCID 4712192Methanone, (3-hydroxybenzo[b]thien-2-yl)phenyl-

HCID 534383891-Butanamine, acetate

Product 1

HCID 178449011HCID 178449011, compoundYield 64%

Procedure

Prepared as in Example 35 from 2-benzoyl-benzo[b]thiophen-3-ol and n-butylammonium acetate with a yield of 64% of theory; m.p. 106°-107° C. (petroleum ether/ethyl acetate 1:1).

Sources & evidence

ORD record: ord-5f0ea4ce029942d584abca2892542b03
Source dataset: uspto-grants-1981_09
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04288437

Reaction notes

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