4-Nitrobenzenesulfonyl chloride → 2-(3-Nitrophenyl)ethyl 4-nitrobenzenesulfonate

HRID 15780

Reaction equation

HRID 15780 reaction equation
[CH3:1][S:2]([O:5][CH2:6][CH2:7][C:8]1[CH:13]=[CH:12][CH:11]=[C:10]([N+:14]([O-:16])=[O:15])[CH:9]=1)(=[O:4])=[O:3].[N+:17]([C:20]1[CH:21]=[C:22](CCO)C=[CH:24][CH:25]=1)([O-:19])=[O:18].[N+](C1C=CC(S(Cl)(=O)=O)=CC=1)([O-])=O>>[N+:17]([C:20]1[CH:21]=[CH:22][C:1]([S:2]([O:5][CH2:6][CH2:7][C:8]2[CH:13]=[CH:12][CH:11]=[C:10]([N+:14]([O-:16])=[O:15])[CH:9]=2)(=[O:3])=[O:4])=[CH:24][CH:25]=1)([O-:19])=[O:18]

Participants

4

Reactant 3

HCID 74044-Nitrobenzenesulfonyl chlorideHCID 1040583-Nitrophenylethyl alcoholHCID 219738843-Nitrophenethyl methanesulfonate

Product 1

HCID 574442742-(3-Nitrophenyl)ethyl 4-nitrobenzenesulfonateYield 68%

Procedure

The title compound was prepared in 68% yield using a similar procedure to description D4 starting from 2-(3-nitro-phenyl)ethanol and 4-nitrobenzenesulfonyl chloride.

Sources & evidence

ORD record
ord-eef2bf9053ff4888bea3fdbe16ca0553
Source dataset
uspto-grants-2010_06
Patent number
US07732600B2

Linked notes

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