Sodium (2R,3R,4S)-2,3,4,6-tetrahydroxy-5-oxohexyl phosphate → Fructose 6-phosphate

HRID 1578065

Reaction equation

HRID 1578065 reaction equation
[P:1]([O:5][CH2:6][C@@H:7]([OH:16])[C@@H:8]([OH:15])[C@H:9]([OH:14])[C:10](=[O:13])[CH2:11][OH:12])([O-:4])([O-:3])=[O:2].[Na+].[Na+]>O>[P:1]([O:5][CH2:6][C@@H:7]([OH:16])[C@@H:8]([OH:15])[C@H:9]([OH:14])[C:10](=[O:13])[CH2:11][OH:12])([OH:3])([OH:4])=[O:2]

Participants

3

Reactant 1

HCID 22812950Sodium (2R,3R,4S)-2,3,4,6-tetrahydroxy-5-oxohexyl phosphate

Product 1

HCID 69507Fructose 6-phosphateYield 93.5%

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

To 18.5 ml of 0.67 M cis-[Pt(NH3)2 (H2O)2 ](NO3)2, 4.5 grams of disodium D-fructose-6-phosphate were added. The solution was stoppered with a porous plug and stirred for 49 days. At the end of that time, a blue, water-insoluble precipitate had formed. It was collected, and then washed by alternate centrifugation and resuspension. The precipitate was vacuum dried to yield 3.6 grams of the above-identified complex.

Workup

  1. customIt was collected
  2. washwashed by alternate centrifugation and resuspension
  3. customdried

Sources & evidence

ORD record
ord-9fc5e58ede8b45ccb14912251ae4ff92
Source dataset
uspto-grants-1981_09
Patent number
US04291023

Linked notes

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