2,4,6-Tribromophenol → HCID 22594837, compound

HRID 1579925

Reaction equation

HRID 1579925 reaction equation
[Br:1][C:2]1[CH:7]=[C:6]([Br:8])[CH:5]=[C:4]([Br:9])[C:3]=1[OH:10].[CH2:11]1[O:13][CH2:12]1>[Cl-].C[N+](C)(C)C.C1C=CC=CC=1>[Br:1][C:2]1[CH:7]=[C:6]([Br:8])[CH:5]=[C:4]([Br:9])[C:3]=1[O:10][CH:12]([OH:13])[CH3:11]

Participants

5

Reactant 2

HCID 14832,4,6-TribromophenolHCID 6354Ethylene Oxide

Product 1

HCID 22594837HCID 22594837, compound

Reagents, catalysts & solvents 2

HCID 6379Tetramethylammonium chlorideCatalystHCID 241BenzeneSolvent

Procedure

2,4,6-Tribromophenol (94.9 parts), ethylene oxide (14.7 parts) and tetramethylammonium chloride (2.0 parts) were charged into the same type of reactor as described in Example I. Reactants were heated to 95°-100° C. over 21/2 hours and allowed to react at this temperature for an additional 41/2 hours for the completion of reaction. The product was then dissolved in benzene, washed with water three times, dried with anhydrous sodium sulfate, filtered, and benzene stripped off under vacuum at 40° C. The final product was a slightly colored pasty material having a hydroxyl number of 150.

Workup

  1. temperatureReactants were heated to 95°-100° C. over 21/2 hours
  2. customto react at this temperature for an additional 41/2 hours
  3. customfor the completion of reaction
  4. washwashed with water three times
  5. dry with materialdried with anhydrous sodium sulfate
  6. filtrationfiltered
  7. customstripped off under vacuum at 40° C

Sources & evidence

ORD record
ord-d4c01be3940f49afbaba4a619bb555f9
Source dataset
uspto-grants-1976_01
Patent number
US03932181

Linked notes

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