5-(3-nitrophenyl)tetrazole → HCID 178507542, compound

HRID 1588026Notes

Reaction equation

HRID 1588026 reaction equation
[N+:1]([C:4]1[CH:5]=[C:6]([C:10]2[NH:14][N:13]=[N:12][N:11]=2)[CH:7]=[CH:8][CH:9]=1)([O-])=O>C(O)C.[Pd]>[NH2:1][C:4]1[CH:5]=[C:6]([C:10]2[NH:14][N:13]=[N:12][N:11]=2)[CH:7]=[CH:8][CH:9]=1

Participants

4

Reactant 1

HCID 2851295-(3-nitrophenyl)tetrazole

Product 1

HCID 178507542HCID 178507542, compound

Reagents, catalysts & solvents 2

HCID 23938PalladiumCatalystHCID 702EthanolSolvent

Procedure

3-Nitro-(1H-tetrazol-5-yl)benzene was dissolved in 200 ml of ethanol, treated with 1.7 g of 10% palladium/carbon catalyst, and hydrogenated on a Parr apparatus at 30 psi for 2 hours. The reaction mixture was filtered through Celite and concentrated to give 4.7 g of the title compound.

Workup

  1. filtrationThe reaction mixture was filtered through Celite
  2. concentrationconcentrated

Sources & evidence

ORD record
ord-8011f81aac654496807dfbdc36505afe
Source dataset
uspto-grants-1993_06
Patent number
US05220018

Reaction notes

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