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Dimethyl Sulfoxide → 2-{[(Ethenyloxy)carbonyl]oxy}ethyl 2-methylprop-2-enoate

HRID 1595036
Notes
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Reaction equation

HRID 1595036 reaction equation
[C:1](=[O:15])([O:12][CH:13]=[CH2:14])[O:2][C:3]1[CH:8]=CC([N+]([O-])=O)=CC=1.OCC[O:19][C:20](=[O:24])[C:21]([CH3:23])=[CH2:22].CS(C)=O.[OH-].[Na+]>O>[C:1](=[O:15])([O:12][CH:13]=[CH2:14])[O:2][CH2:3][CH2:8][O:24][C:20](=[O:19])[C:21]([CH3:23])=[CH2:22]
ParticipantsProcedureWorkupSources & evidenceReaction notes

Participants

6

Reactant 4

HCID 679Dimethyl SulfoxideHCID 133602-Hydroxyethyl MethacrylateHCID 14798Sodium HydroxideHCID 11183405p-Nitrophenyl vinyl carbonate

Product 1

HCID 231870742-{[(Ethenyloxy)carbonyl]oxy}ethyl 2-methylprop-2-enoate

Reagents, catalysts & solvents 1

HCID 962
Water
Solvent

Procedure

A solution of p-nitrophenyl vinyl carbonate, hydroxyethylmethacrylate, DMSO and sodium hydroxide is stirred at room temperature for a minimum of 12 hours. Reaction completion is monitored by G.C. The solution is drowned into water and the mixture extracted with ethyl acetate. The product solution is washed with water, dried with magnesium sulfate, then stripped to an oil under vacuum. The crude product is then purified.

Workup

  1. customReaction completion
  2. extractionthe mixture extracted with ethyl acetate
  3. washThe product solution is washed with water
  4. dry with materialdried with magnesium sulfate
  5. customThe crude product is then purified

Sources & evidence

ORD record
ord-0b3693a52651458e9e1415526eb7797c
Source dataset
uspto-grants-2001_09
DOI
10.6084/m9.figshare.5104873.v1
Patent number
US06284911B1

Reaction notes

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On this pageParticipantsProcedureWorkupSources & evidenceReaction notes