1,9-Decadiene → (7-Octenyl)oxirane

HRID 1608730

Reaction equation

HRID 1608730 reaction equation
[CH2:1]1[O:3][CH:2]1[CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH:10]1O[CH2:11]1.C=CCCCCCCC=C>>[O:3]1[CH:2]([CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH:10]=[CH2:11])[CH2:1]1

Participants

3

Reactant 2

HCID 154391,9-DecadieneHCID 32721Oxirane, 2,2'-(1,6-hexanediyl)bis-

Product 1

HCID 543758(7-Octenyl)oxiraneYield 54%

Procedure

The organic phase was first rapidly distilled in order to remove the catalyst from it, then was rectified, with 47.0 g (0.276 mol) of 1,2,9,10-diepoxydecane, with a yield of 54%; 1.96 g of unreacted 1,9-decadiene (3%); and 23.0 g of 1,2-epoxy-9-decene (29%) being obtained.

Workup

  1. distillationThe organic phase was first rapidly distilled in order
  2. customto remove the catalyst from it

Sources & evidence

ORD record
ord-496ccc02d2214184a3fe4aa8afa49f82
Source dataset
uspto-grants-1995_03
Patent number
US05395992

Linked notes

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