Ethanol → HCID 178454912, compound
Reaction equation
C(OC([P:9]([CH2:14][CH2:15][CH2:16][CH3:17])(=[O:13])[O:10][CH2:11][CH3:12])(OCC)C)C.C(O)C.C[Si](C)(C)Cl>ClCCl>[CH2:14]([PH:9](=[O:13])[O:10][CH2:11][CH3:12])[CH2:15][CH2:16][CH3:17]Participants
5
Reactant 3
Product 1
Reagents, catalysts & solvents 1
Procedure
A solution of 176 g of ethyl 1,1-diethoxyethyl(n-butyl)phosphinate in 540 ml of absolute dichloromethane containing 10% of absolute ethanol is treated with 143.6 g of trimethylchlorosilane. After stirring for 48 hours at room temperature, the solvent is removed in vacuo to afford a pale yellow oil. Distillation in vacuo affords ethyl n-butyl-phosphinate, b.p. 27°-34° (2×10-2 mbar).
Workup
- customthe solvent is removed in vacuo
- customto afford a pale yellow oil
- distillationDistillation in vacuo
Sources & evidence
- ORD record
- ord-744f3f5843174b4ebe1e84da4492a6e8
- Source dataset
- uspto-grants-1993_03
- Patent number
- US05190933
Reaction notes
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