HCID 20238752, compound → 4-(3-Nitrophenoxy)phenol

Reaction equation

[N+:1]([C:4]1[CH:5]=[C:6]([CH:16]=[CH:17][CH:18]=1)[O:7][C:8]1[CH:13]=[CH:12][C:11]([O:14]C)=[CH:10][CH:9]=1)([O-:3])=[O:2].Br.C(O)(=O)C>>[N+:1]([C:4]1[CH:5]=[C:6]([CH:16]=[CH:17][CH:18]=1)[O:7][C:8]1[CH:13]=[CH:12][C:11]([OH:14])=[CH:10][CH:9]=1)([O-:3])=[O:2]

Participants

Reactant 2

HCID 20238752HCID 20238752, compound

HCID 21893785Acetic Acid Mixture with Hydrobromic Acid

Product 1

HCID 132661534-(3-Nitrophenoxy)phenol

Procedure

m-nitrophenol and bromoanisole yield p-(m-nitrophenoxy)anisole of m.p. 69°-71° C. and reaction with hydrobromic acid/acetic acid yields p-(m-nitrophenoxy)phenol which distils in the bulb-tube at 95°-97° C./0.04 Torr;

Sources & evidence

ORD record: ord-32d11cfe8a8646418751be4e06122c6d
Source dataset: uspto-grants-1983_11
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04413010

Reaction notes

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