2-(p-Nitrobenzal)-cyclohexanone → 1-(N-Dimethylaminoethoxyimino)-2-(p-nitrobenzal)-cyclohexane

Reaction equation

Cl.[CH3:2][N:3]([CH2:5][CH2:6][O:7][NH2:8])[CH3:4].[N+:9]([C:12]1[CH:25]=[CH:24][C:15]([CH:16]=[C:17]2[CH2:22][CH2:21][CH2:20][CH2:19][C:18]2=O)=[CH:14][CH:13]=1)([O-:11])=[O:10]>>[CH3:2][N:3]([CH2:5][CH2:6][O:7][N:8]=[C:18]1[CH2:19][CH2:20][CH2:21][CH2:22][C:17]1=[CH:16][C:15]1[CH:14]=[CH:13][C:12]([N+:9]([O-:11])=[O:10])=[CH:25][CH:24]=1)[CH3:4]

Participants

Reactant 2

HCID 2797402-(p-Nitrobenzal)-cyclohexanone

HCID 21928691Dimethylaminoethoxyamine hydrochloride

Product 1

HCID 1317110451-(N-Dimethylaminoethoxyimino)-2-(p-nitrobenzal)-cyclohexane

Procedure

On starting from 17.7 g (0.1 moles) of dimethylaminoethoxyamine hydrochloride and 23.1 g (0.1 moles) of 2-(p-nitrobenzal)-cyclohexanone, one proceeds in the way as specified in Example 32.

Sources & evidence

ORD record: ord-e2b37bd1f59e41d4a7326dbac9558eed
Source dataset: uspto-grants-1978_03
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04077999

Reaction notes

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