Allyl chloride → Trichloro(2,4,4-trimethylpentyl)silane

HRID 1680910

Reaction equation

[Cl:1][SiH:2]([Cl:4])[Cl:3].[CH3:5][C:6]([CH2:8][C:9]([CH3:12])([CH3:11])[CH3:10])=[CH2:7].CC(C)=CC(C)(C)C.C(Cl)C=C>>[CH3:5][CH:6]([CH2:8][C:9]([CH3:12])([CH3:11])[CH3:10])[CH2:7][Si:2]([Cl:4])([Cl:3])[Cl:1]

Participants

Reactant 4

HCID 7850Allyl chloride

HCID 78682,4,4-Trimethyl-1-pentene2×

HCID 78692,4,4-Trimethyl-2-pentene

HCID 24811Trichlorosilane3×

Product 1

HCID 86714Trichloro(2,4,4-trimethylpentyl)silane

Procedure

The process described in Example 2 is repeated, except that 1.2 liters of trichlorosilane, 1.8 liters of diisobutylene (a mixture of 2,4,4-trimethylpentene-1 and 2,4,4-trimethylpentene-2) and 10 ml of the catalytic solution are substituted for the trichlorosilane, allyl chloride and catalytic solution. About 98.6 mol percent of the trichlorosilane employed is reacted and 11.6 moles per hour of 2,4,4-trimethylpentyltrichlorosilane are obtained.

Sources & evidence

ORD record: ord-b643a7355bf94b5bb75ce21e901fbfa5
Source dataset: uspto-grants-1981_06
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04276426

Linked notes

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