HuagongsheHuagongshe Chemistry Print Report · For research reference only
2-Chlorocyclohexanone → 2-Methyl-2,3,5,6,7,8-hexahydro-1,4-benzodithiine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2-Chlorocyclohexanone | HCID 13203 | — |
| Reactant | 2,3-Dimercaptopropane | HCID 61217 | — |
| Product | 2-Methyl-2,3,5,6,7,8-hexahydro-1,4-benzodithiine | HCID 12920049 | 66% |
Reaction Steps
The procedure of Example 1(a) is followed using 2-chloro-cyclohexanone and 1,2-propanedithiol to give 5,6,7,8-tetrahydro-2-methyl-1,4-benzodithian as a greenish oil, bp 127°-130°/2.3 mm, Yield 66%. NMR, 1.36 (3d), 1.4-1.88 (4m), 1.88-2.3 (4m), 2.6-3.7 (3m). IR, 2920, 1615, 1410, 1325, 1250, 1120, 855, 715.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04276422 |
| Source dataset | uspto-grants-1981_06 |
| ORD ID | ord-2580f628896944a48ab0397a0249e23b |
| Source note | uspto-grants-1981_06 |