Diisopentyl ether → diisoamyl ether DEAC

HRID 1681683Notes

Reaction equation

HRID 1681683 reaction equation
[Cl-:1].[CH2:2]([Al+:4][CH2:5][CH3:6])[CH3:3].[CH2:7]([O:12][CH2:13][CH2:14][CH:15]([CH3:17])[CH3:16])[CH2:8][CH:9]([CH3:11])[CH3:10]>[Cl-].[Cl-].[Cl-].[Ti+3].CCCCCC>[CH2:13]([O:12][CH2:7][CH2:8][CH:9]([CH3:11])[CH3:10])[CH2:14][CH:15]([CH3:16])[CH3:17].[Cl-:1].[CH2:2]([Al+:4][CH2:5][CH3:6])[CH3:3]

Participants

5

Reactant 2

HCID 10989Diisopentyl etherHCID 16686102Diethyl aluminum chloride

Product 1

HCID 131713250diisoamyl ether DEAC

Reagents, catalysts & solvents 2

HCID 10313229titanium(III) trichlorideCatalystHCID 8058HexaneSolvent

Procedure

Preparation of titanium trichloride composition-n-Hexane (6 l), diethylaluminum monochloride (DEAC) (5.0 mols) and diisoamyl ether (12.0 mols) were mixed at 25° C. for 5 minutes, followed by reacting the mixture at the same temperature, for 15 minutes to obtain a reaction solution (I) (the molar ratio of diisoamyl ether/DEAC: 2.4).

Workup

  1. additionwere mixed at 25° C. for 5 minutes

Sources & evidence

ORD record
ord-2afcdbcb04a0490fad9c60a07db7fe7c
Source dataset
uspto-grants-1992_12
Patent number
US05173540

Reaction notes

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