2,4-Bis(propan-2-yl)aniline → 2-Isopropylaniline

Reaction equation

[CH:1]([C:4]1[CH:10]=[C:9](C(C)C)[CH:8]=[CH:7][C:5]=1[NH2:6])([CH3:3])[CH3:2].C(C1C=CC(C(C)C)=CC=1N)(C)C>>[CH:1]([C:4]1[CH:10]=[CH:9][CH:8]=[CH:7][C:5]=1[NH2:6])([CH3:3])[CH3:2]

Participants

Reactant 2

HCID 127501082,4-Bis(propan-2-yl)aniline

HCID 154426012,5-Bis(propan-2-yl)aniline

Product 1

HCID 125612-Isopropylaniline

Procedure

If the procedure described above is used, but replacing the 2,4-diisopropylaniline by the same amount of 2,5-diisopropylaniline or by 99 parts of 2-isopropylaniline, perylenetetracarboxylic acid N,N'-bis-(2',5'-diisopropylanilide) and N,N'-bis-(2'-isopropylanilide), respectively, are obtained in very good yield.

Sources & evidence

ORD record: ord-d7713a01f5f94dbba45505944345ffe6
Source dataset: uspto-grants-1983_04
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04379934

Reaction notes

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