Phosphine, bis(2-methylpropyl)- → HCID 131727269, compound

HRID 1724102Notes

Reaction equation

HRID 1724102 reaction equation
[CH2:1]([PH:5][CH2:6][CH:7]([CH3:9])[CH3:8])[CH:2]([CH3:4])[CH3:3].CN([CH2:13][C-:14]1[CH:18]=[CH:17][CH:16]=[C:15]1[CH2:19]N(C)C)C.[CH-:23]1[CH:27]=[CH:26][CH:25]=[CH:24]1.[Fe+2:28]>C(O)(=O)C>[CH2:1]([P:5]([CH2:13][C-:14]1[CH:18]=[CH:17][CH:16]=[C:15]1[CH2:19][P:5]([CH2:6][CH:27]([CH3:26])[CH3:23])[CH2:1][CH:2]([CH3:4])[CH3:3])[CH2:6][CH:7]([CH3:9])[CH3:8])[CH:2]([CH3:4])[CH3:3].[CH-:23]1[CH:27]=[CH:26][CH:25]=[CH:24]1.[Fe+2:28]

Participants

4

Reactant 2

HCID 77622Phosphine, bis(2-methylpropyl)-HCID 1317272661,2-Bis(dimethylaminomethyl)ferrocene

Product 1

HCID 131727269HCID 131727269, compound

Reagents, catalysts & solvents 1

HCID 176Acetic AcidSolvent

Procedure

The title compound was prepared in accordance with the procedure of Example 2 employing di-iso-butylphosphine (Strem 486 mg, 3.33 mmol), 1,2-bis(dimethylaminomethyl)ferrocene (0.5 g, 1.66 mmol) and anhydrous acetic acid (100 ml). Yield 0.372 g.

Sources & evidence

ORD record
ord-d5127394984f437ea51dedad4d3435fa
Source dataset
uspto-grants-2009_02
Patent number
US07485739B2

Reaction notes

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