Adamantanone → N'-(adamantan-2-ylidene)(tert-butoxy)carbohydrazide

HRID 1737916Notes

Reaction equation

HRID 1737916 reaction equation
[CH:1]12[CH2:10][CH:5]3[CH2:6][CH:7]([CH2:9][CH:3]([CH2:4]3)[C:2]1=O)[CH2:8]2.[C:12]([O:16][C:17]([CH3:20])([CH3:19])[CH3:18])(=[O:15])[NH:13][NH2:14]>CCCCCC>[CH:1]12[CH2:10][CH:5]3[CH2:6][CH:7]([CH2:9][CH:3]([CH2:4]3)[C:2]1=[N:14][NH:13][C:12]([O:16][C:17]([CH3:20])([CH3:19])[CH3:18])=[O:15])[CH2:8]2

Participants

4

Reactant 2

HCID 64151AdamantanoneHCID 70091tert-Butyl carbazate

Product 1

HCID 8039095N'-(adamantan-2-ylidene)(tert-butoxy)carbohydrazide

Reagents, catalysts & solvents 1

HCID 8058HexaneSolvent

Procedure

A hexane solution containing 2-adamantanone (2 g) and tert-butyl carbazate (1.76 g) was heated to reflux for 3 hours. When the solution cooled, the title compound crystallized and was filtered (3.28 g). M.p. 175-177°

Workup

  1. temperaturewas heated
  2. temperatureto reflux for 3 hours
  3. temperatureWhen the solution cooled
  4. customthe title compound crystallized
  5. filtrationwas filtered (3.28 g)

Sources & evidence

ORD record
ord-fde0bd09b7b94d7b8dfc18b83e4509a4
Source dataset
uspto-grants-1999_10
Patent number
US05962496

Reaction notes

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