2-(Trimethylstannyl)-1,3-thiazole → HCID 19390976, compound

Reaction equation

[NH2:1][C:2]1[N:6]([C:7]2[CH:12]=[CH:11][CH:10]=[C:9](I)[CH:8]=2)[C:5]2[CH:14]=[CH:15][CH:16]=[CH:17][C:4]=2[N:3]=1.C[Sn](C)(C)[C:20]1[S:21][CH:22]=[CH:23][N:24]=1>>[NH2:1][C:2]1[N:6]([C:7]2[CH:12]=[CH:11][CH:10]=[C:9]([C:20]3[S:21][CH:22]=[CH:23][N:24]=3)[CH:8]=2)[C:5]2[CH:14]=[CH:15][CH:16]=[CH:17][C:4]=2[N:3]=1

Participants

Reactant 2

HCID 129566412-(Trimethylstannyl)-1,3-thiazole

HCID 19390960Amino-1-(3-iodophenyl)-benzimidazole

Product 1

HCID 19390976HCID 19390976, compound

Procedure

2-Amino-1-[3(2-thiazolyl)phenyl]benzimidazole was prepared from 1-(2-amino-1-benzimidazolyl)-3-iodobenzene and 2-trimethylstannylthiazole by method C. mp 224°-226° C.

Sources & evidence

ORD record: ord-3a9ce2643160452a8d6d620cc3815a7c
Source dataset: uspto-grants-1995_08
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05441969

Reaction notes

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